PSG, who last won the tournament in 2010 and will host the fixture, saw off Monaco to book their place in the last four, while Saint-Etienne required penalties to defeat third-tier outfit Boulogne.
Guingamp are the defending champions and will be fancied to reach a second successive final having been handed a tie at Ligue 2 side Auxerre.
The fixtures are set to take place on April 7 and 8.
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