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Having conquered Europe as Porto coach in 2004 and last season with Inter Milan, the Portuguese has taken his special qualities to the Bernabeu having replaced Manuel Pellegrini.
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"Real Madrid want their 10th (European Cup) just as much as I want my third but we both know it's very difficult," Mourinho told a news conference on Tuesday.
Last season's runners-up Bayern Munich begin in Group E against AS Roma while English double winners Chelsea travel to Slovakia to play new boys MSK Zilina in Group F.
