Barca, in the final for the second time in three years, built on their lead from an ill-tempered first leg in Madrid when Pedro rifled in after 54 minutes.
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"There has been a great deal of effort behind this, a team that returned from the World Cup almost without having a break," Barca coach Pep Guardiola told Spanish television referring to the players who were world champions with Spain last year.
"Just let us enjoy this moment," he added, when asked about the controversy of recent weeks.
Barca's success was payback for last month's King's Cup Final defeat, as well as giving them a measure of revenge over Real coach Jose Mourinho.
The Portuguese, who was absent from the bench after being sent to the stands in last week's first leg, knocked the Catalan club out at the same stage last season with Inter Milan before leading the Italian club to victory in the final.
Real's players spent long periods chasing the ball as the Barca players sent it fizzing across the slick surface and they would have been out of sight by halftime if not for a slew of brilliant saves from goalkeeper Iker Casillas.
The Spanish World Cup-winner was finally beaten when Pedro raced on to Andres Iniesta's through ball and slotted into the corner.
While there was no repeat of the ugly scenes that marred last week's ill-tempered first leg, referee Frank de Bleeckere brandished six yellow cards - five to Real players - in another tetchy contest.
World Player of the Year Lionel Messi, who scored both goals in the first leg and is the competition's top scorer with 11, was a near-constant threat to the Real goal in the first half and was twice denied by superb Casillas saves.
The Argentina forward released striker David Villa into space in the 34th minute but Casillas was equal to his Spain team mate's curling shot.
As the match wore on, Mourinho's assistant, Aitor Karanka, and the Real players appeared powerless in the face of the relentless Barca tackling and possession and they managed just one shot on target to Barca's six.
"We have to lift our heads up and be proud," Real captain Casillas said in an interview with Spanish television as the Barca players celebrated wildly on the pitch.
"Anything we say now could be used against us," he added, re
