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Two second-half goals to Tucanes' Livingston Adjin and Argenis Gomez secured a 2-0 win at home against Deportivo Anzoategui.
Adjin struck with a fine finish on 67 minutes before Gomez made the result safe with a strike in second-half stoppage time.
The defeat was Petare's third consecutive to start the season, joining Llaneros de Guanare and Atletico El Vigia at the bottom of the Primera A table.
After being a goal up heading into second-half stoppage time, El Vigia contrived to earn nothing from their match with Luis Salmeron's two penalties in the dying moments ensuring Atletico Venezuela clinched a 2-1 win.
Zulia's Daniel Arismendi put Llaneros de Guanare to the sword with a goal on 73 minutes to secure a 1-0 triumph.
