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Gonzalo Higuaín Napoli lost top spot in the Serie A on the weekend but will hope to bounce back in Spain as the Europa League resumes.
Jurgen Klopp made a low-key Anfield debut as Liverpool were frustrated by Rubin Kazan, while Anderlecht beat Tottenham.
Porto's hopes of winning the Primeira Liga are over after they were held by Belenenses and Benfica drew with Vitoria Guimaraes.
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There was more disappointment for Liverpool in the Europa League, while Marseille suffered a surprise home defeat.
Rodrigo Lima Dos Santos Benfica ran riot to relegate Penafiel as the Primeira Liga leaders moved six points clear at the summit.
Benfica Benfica put in four goals to celebrate being handed the Primeira Liga trophy in style on Saturday.
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